Aggregation of Surfactants: Catalytic Reinforcement in Oxidation of Unsaturated E-Crotonaldehyde-Reference-Cited by-同舟云学术

Aggregation of Surfactants: Catalytic Reinforcement in Oxidation of Unsaturated E-Crotonaldehyde

Published:2021-07-01 Issue:4 Volume:58 Page:293-302
ISSN:2195-8564
Container-title:Tenside Surfactants Detergents
language:en
Short-container-title:

Author:

Rakshit Atanu¹,Chowdhury Suman¹,Acharjee Animesh¹²,Dome Kuheli³,Karmakar Kripasindhu¹,Saha Bidyut¹

Affiliation:

1. Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan , Burdwan 713104 , WB, India

2. Department of Chemistry, Hooghly Mohsin College , Chinsurah, WB , India

3. Department of Chemistry, IIT (ISM), Dhanbad , Jharkhand 826004 , India

Abstract

Abstract In this work, the kinetics of the micellar catalyzed oxidation of the unsaturated aliphatic aldehyde, E-crotonaldehyde in aqueous medium under pseudo 1st-order reaction condition was spectrophotometrically investigated at 25 °C. In the spectrophotometric measurement, the rate of the reaction was recorded by the decreasing intensity of the metallic oxidant, hexavalent chromium [Cr(VI)], in acidic aliquots at 450 nm with varying concentration of surfactants and/or heteroaromatic promoters. Spectral evidences have been produced in favour of the mechanistic approach and the product formation.

Publisher

Walter de Gruyter GmbH

Subject

Condensed Matter Physics,General Chemical Engineering,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/tsd-2020-2336/pdf

Reference30 articles.

1. Lipshutz, B. H., Ghorai, S. and Cortes-Clerget, M.: The Hydrophobic Effect Applied to Organic Synthesis: Recent Synthetic Chemistry \in Water". Chem. Eur. J. 24 (2018) 6672–6695. PMid:29465785; DOI:10.1002/chem.201705499

2. Sorella, G. L., Strukul, G. and Scarso, A.: Recent advances in catalysis in micellar media. Green Chem. 17 (2015) 644–683. DOI:10.1039/C4GC01368A

3. Mandal, S., Mandal, S., Biswas, S. and Saha, B.: Synthesis of 4-Hydroxy-4-(4-nitrophenyl)butan-2-one using p-Nitro Benzaldehyde and Acetone in Aqueous Micellar Media using L-Proline. Tenside Surf. Det. 55 (2018) 325–330. DOI:10.3139/113.110566

4. Mandal, S., Mandal, S., Biswas, S., Mondal, M. H. and Saha, B.: Synthesis of 2-(Prop-2-ynyloxy) Benzaldehyde using Salicyl Aldehyde and Propargyl Bromide in Aqueous Micellar Media. Tenside Surf. Det. 56 (2019) 337–342. DOI:10.3139/113.110629

5. Acharjee, A., Rakshit, A., Chowdhury, S. and Saha, B.: Micellar and Transition Metal Ion Catalysed Oxidation of Pentanol in Aqueous Medium. Tenside Surf. Det. 57 (2020) 506–514. DOI:10.3139/113.110709