Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides-Reference-Cited by-同舟云学术

Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides

Published:1999-07-01 Issue:7 Volume:54 Page:858-862
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Braun Thomas P.¹²,Gutsch Paul A.¹,Zimmer Hans¹

Affiliation:

1. Dept. of Chemistry, University of Cincinnati, Cincinnati. OH 45221-0172, USA

2. Present address: Dept. of Chemistry, Cornell University, Ithaca, NY 14853-1301, USA

Abstract

The synthesis, IR and 31P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported. It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl2 that in the solid state these complexes form dimers via two Hg ∙∙∙ μ2- Cl ∙∙∙ Hg bridges.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1999-0706/pdf

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