Electronic versus steric control in palladium complexes of carboranyl phosphine-iminophosphorane ligands-Reference-Cited by-同舟云学术

Electronic versus steric control in palladium complexes of carboranyl phosphine-iminophosphorane ligands

Published:2019 Issue:2 Volume:48 Page:486-503
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rodríguez-Rey José Luis¹²³⁴,Esteban-Gómez David⁵⁶⁷⁴,Platas-Iglesias Carlos⁵⁶⁷⁴,Sousa-Pedrares Antonio¹²³⁴^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Universidade de Santiago de Compostela

3. 15782 Santiago de Compostela

4. Spain

5. Centro de Investigacións Científicas Avanzadas (CICA) and Departamento de Química

6. Universidade da Coruña

7. 15008 A Coruña

Abstract

Subtle changes in the electronic properties of C- and B3-carboranyl phosphineiminophosphoranes allows a fine control of the donor ability of the imine nitrogen atom, which results in Pd complexes with the ligands providing (P,N)-chelating or P-terminal coordination.

Funder

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04006K

Reference114 articles.

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