Affiliation:
1. Department of Chemistry, Faculty of Science, Hiroshima University, Higashisenda-machi, Naica-ku, Hiroshima 730
Abstract
Abstract
In a series of MSnI3 compounds (M = K, NH4 , Rb, Cs, CH3NH3) two types of coordination around the central Sn(II) were found by 127I-NQR and powder X-ray diffraction techniques. They are square pyramidal (for M = NH4 , Rb) and octahedral (for M = CH3NH3). CsSnI3 , on the other hand, showed a drastic structural change of the anion at 425 K from a square pyramid to a regular octahedron. Associated with this phase transition, the electrical conductivity increased from 4 x 10-3 S cm-1 to about 102 S cm-1 . This metallic modification was characterized by 127I-NQR and 119Sn Mössbauer spectroscopy.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
38 articles.
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