The crystal structure of carbonyl-[4-(2,4-dichlorophenylamino)pent-3-en-2-onato-κ2N,O]-(triphenylphosphine-κP)rhodium(I), RhC30H25Cl2NO2P

Author:

Venter Gertruida J.S.1

Affiliation:

1. Department of Chemistry, University of the Free State, P.O. Box 339, Bloemfontein 9300, South Africa

Abstract

AbstractRhC30H25Cl2NO2P, orthorhombic P212121 (no. 19), a = 7.6656(5) Å, b = 16.6097(11) Å, c = 20.9423(14) Å, V = 2666.4(3) Å3, Z = 4, Rgt(F) = 0.0649, wRref(F2) = 0.1632, T = 100 K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference30 articles.

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2. The nature of halogen⋯halogen synthons: crystallographic and theoretical studies;Chem. Eur. J,2006

3. Crystal structure of carbonyl-(4-(2,6-dichlorophenylamino)pent-3-en-2-onato-κ2N,O)-(triphenylphosphine-κP)-rhodium(I) acetone solvate, C31.5H28Cl2NO2.5PRh;Z. Kristallogr. NCS,2013

4. Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis;Chem. Rev,1977

5. Carbonyl[4-(2,6-dimethylphenylamino)-pent-3-en-2-onato-κ2N,O](triphenylphosphine-kP)rhodium(I) acetone hemisolvate;Acta Crystallogr,2009

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