Crystal structure of monocarbonyl[2-((cyclopentylmethylene)amino)-5-methylphenolato-κ2N,O] (tricyclohexylphosphine)rhodium(I), C32H48NO2PRh

Author:

Mokolokolo Pennie P.1,Alexander Orbett T.1,Schutte-Smith Marietjie1,Brink Alice1,Roodt Andreas1

Affiliation:

1. Department of Chemistry, University of the Free State, Bloemfontein 9301, South Africa

Abstract

AbstractC32H48NO2PRh, orthorhombic, P212121 (no. 19), a = 26.784(10) Å, b = 8.837(3) Å, c = 12.759(4) Å, V = 3020.0(18) Å3, Z = 4, Rgt(F) = 0.0400, wRref(F2) = 0.0920, T = 100(2) K.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference44 articles.

1. The crystal structure of thioacetylacetonatocarbonyltriphenylphosphinerhodium(I);Inorg. Chim. Acta,1987

2. The crystal structure of 8-hydroxyquinolinatocarbonyltriphenyl-phosphinerhodium(I);Inorg. Chim. Acta,1981

3. The crystal structure of 8-hydroxyquinolinatocarbonyltriphenyl-phosphinerhodium(I);Inorg. Chim. Acta,1981

4. The crystal structure of N-o-tolylsalicylaldiminatocarbonyl-triphenylphosphinerhodium(I);Inorg. Chim. Acta,1985

5. Steric vs;electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium(I) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl [PR3 = PPh3, PPh2Cy, PPhCy2 and PCy3]. Dalton Trans,2010

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