Inorganic salt hydrates and zeolites composites studies for thermochemical heat storage

Author:

Rehman Ata Ur123ORCID,Shah Muhammad Zahir1ORCID,Rasheed Shehla4,Afzal Wasim1,Arsalan Muhammad5,Rahman Habib Ur6,Ullah Mati7,Zhao Tianyu2,Ullah Ihsan8,Din Ala Ud9,Ullah Saif10,Shah Rahim11,Iqbal Muhammad3,Maosheng Zheng2,Guan Zheng-Hui1ORCID

Affiliation:

1. Department of Chemistry & Materials Science , Key Laboratory of Synthesis and Natural Function Molecules Chemistry of Ministry of Education, Northwest University , Xi’an , P. R. China

2. School of Chemical Engineering , Institute for Energy Transmission Technology and Application, Northwest University , Xi’an , Shaanxi 710069 , P. R. China

3. Department of Chemistry , Bacha Khan University , Charsadda , Pakistan

4. Fatima Jinnah Women University , Rawalpindi , Pakistan

5. Department of Chemistry & Materials Science , Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry, Northwest University , Xi’an , Shaanxi 710069 , P. R. China

6. School of Chemistry and Material Sciences , Institute of Modern Separation Science, Northwest University , Xi’an , Shaanxi 710069 , P. R. China

7. Department of Physics , University of Haripur , Haripur , Pakistan

8. School of Material Science and Engineering , Changwon National University , Gyeongnam , 51140 , Republic of Korea

9. Department of Chemistry , University of Buner , Buner , 17290 , Pakistan

10. Department of Chemistry , Anhui University , Hefei , 230601 , P. R. China

11. School of Physics , University of Electronic Science and Technology of China , Chengdu , 610054 , P. R. China

Abstract

Abstract Salt hydrates (MgSO4 and ZnSO4) impregnated in zeolites, offer a variety of improvements, mostly providing a large surface area for salt hydrates and water molecules. A composite of 5 and 10% of salt contents were prepared as heat storage materials. The study’s finding showed that dehydration enthalpy of MgSO4 (1817 J g−1) and ZnSO4 (1586 J g−1) were 10 and 15% improved than pure salt hydrates by making composites. During the hydration process of composites, the water sorption is 30–37% improved and further the increasing of salt contents in composites enhances more 10% increase in the water resorption. The cyclicability of MgSO4/zeolite and ZnSO4/zeolite were 45 and 51% improved than their corresponding pure salt hydrates. The effect of humidity on the water sorption result reveals that composites of MgSO4/zeolite and ZnSO4/zeolite at 75% relative humidity (RH), the mass of water are 51 and 40% increase than 55% RH.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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