Synthesis of Carboxymethyl Starch-Bio-Based Epoxy Resin and their Impact on Mechanical Properties-Reference-Cited by-同舟云学术

Synthesis of Carboxymethyl Starch-Bio-Based Epoxy Resin and their Impact on Mechanical Properties

Published:2019-08-30 Issue:11-12 Volume:234 Page:1759-1769
ISSN:2196-7156
Container-title:Zeitschrift für Physikalische Chemie
language:en
Short-container-title:

Author:

Aziz Tariq¹,Fan Hong²,Khan Farman Ullah³,Ullah Roh⁴,Haq Fazal²,Iqbal Mudassir²,Ullah Asmat⁵

Affiliation:

1. State Key Laboratory of Chemical Engineering , College of Chemical and Biological Engineering, Zhejiang University , Hangzhou , 310027, China , Tel.: +86 13208010580, e-mail:

2. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering , Zhejiang University , Hangzhou , 310027, China

3. Department of Chemistry , University of Science and Technology , Bannu 28000, Pakistan

4. College of Chemical and Biological Engineering, Beijing Institute of Technology (BIT) , Beijing , China

5. School of Pharmacy, Xi’an Jiaotong University Shannxi , Shaanxi Sheng , China

Abstract

Abstract In the current research, we observed numerous suggestions are promoting the use of bio-based epoxy resins, replacing the petroleum-based products like Diglycidyl ether of bisphenol A type epoxy resin DGEBA. With the passage of time, the impending challenges include preparation of environmentally-friendly epoxy with minimum toxic side effect and improved properties. Therefore, we describe a very useful method for preparing new silicone-bridged dimethyl siloxane monomers in high quantity, derived from naturally occurring eugenol. By putting the methyl siloxane, computed with different chain lengths into their molecular backbone. Such epoxy monomers have different molecular structure with high purity. This dimethyl siloxane epoxy, with lower viscosity than commercial DGEBA epoxy, has superior thermal properties, which were evaluated using differential scanning calorimetry DSC. Modification of CMS increases the hydrophilicity. Bio-based epoxy (self-prepared) resin improved adhesive properties, with the help of modified CMS. This study presents a very easy and effective chemical modification to enhance interfacial adhesion composites with superior properties.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/zpch-2019-1434/pdf

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