Affiliation:
1. 1Lehrstuhl für Anorganische Chemie I (Arbeitsgruppe Festkörperchemie), Ruhr-Universität Bochum, Universitätsstraße 150, D-4630 Bochum 1
Abstract
Abstract The compound KLiS has been prepared and its crystal structure is determined by X-ray diffraction techniques. The hygroscopic, yellow compound crystallizes in the tetragonal space group P4/nmm (Z = 2) with the cell parameters a - 431.79(4), c = 696.20(9) pm. The structure was solved from 2100 counter reflections (356 symmetry independent reflections) through a Patterson synthesis and refinement by Fourier syntheses to a least squares residue of 0.026. The structure is characterized by c-centered squares of lithium layers interspersed by anti-parallel ordered K-S-pairs forming an anti-PbFCl-type geometry.
Cited by
25 articles.
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