Reaktionen von 1-Phenyl-3-alkoxycarbonyl-triazenen mit Lewis-Säuren in Benzol. / Reactions of 1-Phenyl-3-alkoxycarbonyl-triazenes with Lewis Acids in Benzene

Abstract

1-Phenyl-3-alkoxycarbonyl-triazenes react with aluminiumchloride in benzene by elimination of nitrogen, especially to alkylbenzenes and diphenyl; anilin is formed with practical constant yield, independently of the alkyl group. On the basis of these experimental results during the reaction of alkoxycarbonyl azides with benzene under the influence of Lewis acids triazenes are not formed as intermediates