Affiliation:
1. Institut für Organische Chemie der Technischen Hochschule Darmstadt
Abstract
The reaction of aryldiazo-4-tolylsulfones with benzene under the influence of aluminiumchloride has been investigated. Elimination of p-toluene-sulfinic acid is followed by evolution of nitrogen; substituted biphenyls can be isolated as main products. Aryl- and biphenylyl-4-tolyl-sulfoxides are formed by a consecutive process of the sulfinic acid as minor products. The arylation reaction presumably proceeds via the intermediate formation of aryl-diazonium ions.
Cited by
7 articles.
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