Beryllium triflates: synthesis and structure of BeL2(OTf)2 (L=H2O, THF, n Bu2O)-Reference-Cited by-同舟云学术

Beryllium triflates: synthesis and structure of BeL2(OTf)2 (L=H2O, THF, n Bu2O)

Published:2020-03-18 Issue:8-9 Volume:235 Page:263-268
ISSN:2196-7105
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Müller Matthias¹,Buchner Magnus R.¹

Affiliation:

1. Fachbereich Chemie, Philipps-Universität Marburg , Hans-Meerwein-Straße 4 , 35032 Marburg , Germany

Abstract

Abstract Beryllium and BeCl2 were treated with trifluoromethanesulfonic acid and trimethylsilyltriflate, respectively to form beryllium triflates BeL2(OTf)2 (L=H2O, THF, n Bu2O). The Be–O atomic distances (1.605–1.635 Å) between Be2+ and the triflate anions in solid state are the shortest known distances of this kind in a metal triflate yet. Attempts to remove the solvate molecules led to the decomposition of the obtained compounds.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1515/zkri-2020-0016/pdf

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