Behavior of beryllium halides and triflate in acetonitrile solutions

Abstract

Abstract The solution behavior of beryllium halides and triflate in acetonitrile was studied by NMR, IR and Raman spectroscopy. Thereby mononuclear units [(MeCN)2BeX 2] (X = Cl, Br, I, OTf) were identified as dominant species in these solutions. The solid state structure of [(MeCN)2Be(OTf)2] has been determined by X-ray diffraction. If only one equivalent of MeCN is used the dinuclear compounds [(MeCN)BeX 2]2 (X = Cl, Br, I) are formed. Partial halide and triflate dissociation into the monomeric complexes as well as the formation of hetero-halide complexes [(MeCN)2BeClBr], [(MeCN)2BeClI] and [(MeCN)2BeBrI] was observed.