Synthesis, structure, and photocatalytic properties of a two-dimensional uranyl organic framework

Author:

Meng Yuning1,Liu Donghui1,Lan Qiaofa1,Xie Ziyu1,Niu Fei1,Zhang Xiaolin1,Yang Youming1

Affiliation:

1. Faculty of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology , Ganzhou 341000 , P. R. China

Abstract

Abstract A two-dimensional uranyl organic framework (UOF) UO2(L)(DMA) (1) (H2L = 2-aminoisophthalic acid, DMA = N, N-dimethylacetamide) has been solvothermally synthesized and characterized thoroughly by elemental analysis, infrared spectroscopy, single-crystal X-ray diffraction, solid fluorescence, powder X-ray diffraction, thermogravimetric analysis, and UV–visible spectroscopy. Furthermore, the degradation efficiencies of UOF 1 to organic dye methylene blue (MB) and rhodamine B (RhB) are 93.2 and 86.5% under irradiation of visible light which indicates that UOF 1 has remarkable photocatalytic activity. UOF 1 also displayed a certain selectivity for mixed dyes of MB & RhB.

Funder

National Key Research and Development Program of China

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference37 articles.

1. Zhang, M. X., Liang, C. Y., Cheng, G. D., Chen, J. C., Wang, Y. M., He, L. W., Cheng, L. W., Gong, S. C., Zhang, D., Li, J., Hu, S. X., Diwu, J., Wu, G. Z., Wang, Y. X., Chai, Z. F., Wang, S. Intrinsic semiconducting behavior in a large mixed-valent uranium-(V/VI) cluster. Angew. Chem. Int. Ed. 2021, 60, 9886; https://doi.org/10.1002/ange.202017298.

2. Wang, Y. X., Yin, X. M., Liu, W., Xie, J., Chen, J. F., Silver, M. A., Sheng, D. P., Chen, L. H., Diwu, J., Liu, N., Chai, Z. F., Albrecht-Schmitt, T. E., Wang, S. A. Emergence of uranium as a distinct metal center for building intrinsic X-ray scintillators. Angew. Chem. Int. Ed. 2018, 130, 8009; https://doi.org/10.1002/ange.201802865.

3. Xie, J., Wang, Y. X., Liu, W., Yin, X. M., Chen, L. H., Zou, Y. M., Diwu, J., Chai, Z. F., Albrecht-Schmitt, T. E., Liu, G. K., Wang, S. Highly sensitive detection of ionizing radiations by a photoluminescent uranyl organic framework. Angew. Chem. Int. Ed. 2017, 129, 1; https://doi.org/10.1002/ange.201700919.

4. Gui, D. X., Duan, W. C., Shu, J., Zhai, F. W., Wang, N., Wang, X. X., Xie, J., Li, H., Chen, L. H., Diwu, J., Chai, Z. F., Wang, S. Persistent superprotonic conductivity in the order of 10−1 S·cm−1 achieved through thermally induced structural transformation of a uranyl coordination polymer. CCS Chem 2019, 1, 197; https://doi.org/10.31635/ccschem.019.20190004.

5. Liu, C., Yang, X. X., Niu, S., Yi, X. Y., Pan, Q. J. Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation. Dalton Trans. 2020, 49, 4155; https://doi.org/10.1039/d0dt00379d.

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3