Affiliation:
1. School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, P.R. China
2. School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, P.R. China
Abstract
AbstractA novel trisilanol polyhedral oligomeric silsesquioxane-containing phosphorus (DPCP-TPOSS) was synthesized from trisilanolphenyl polyhedral oligomeric silsesquioxane (TPOSS) and diphenyl chlorophosphate. DPCP-TPOSS was characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), hydrogen nuclear magnetic resonance (1H-NMR), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). Then a novel type of room-temperature vulcanized silicone rubber (RTV)/DPCP-TPOSS composite was prepared. Properties such as swelling behavior, tensile strength, elongation at break, thermal stability and flame retardance were researched and compared. Results showed that RTV/DPCP-TPOSS-3 and RTV/DPCP-TPOSS-5 composites exhibited the best tensile strength and elongation at break, 4.5 MPa and 427%, which was 25% and 32% higher than that of pure RTV. TGA tests demonstrated that RTV/DPCP-TPOSS-3 owned the highest char residues, 39.7%. Tmax of RTV composites was increased from 531.9°C to 557°C with the incorporation of DPCP-TPOSS. Moreover, the addition of DPCP-TPOSS led to considerably increase of the fire-retardant performance.
Subject
Polymers and Plastics,Physical and Theoretical Chemistry,General Chemical Engineering
Cited by
12 articles.
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