High-pressure synthesis of borate-nitrates: crystal structure of M
3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+)
Author:
Pasqualini Leonard C.1ORCID, Huppertz Hubert1ORCID
Affiliation:
1. Institut für Allgemeine, Anorganische und Theoretische Chemie, Universität Innsbruck , Innrain 80–82, 6020 , Innsbruck , Austria
Abstract
Abstract
The orthorhombic nitrate-boracites with the sum formula M
3B7O13NO3 (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+) were synthesized in a Walker-type multianvil apparatus under high-pressure/high-temperature conditions of 6 GPa and 800 °C, respectively. The crystal structures of the five isotypic substances, which crystallize in the space group Pca21, were determined via single-crystal X-ray diffraction and the structural features of the incorporated nitrate anions are discussed.
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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