Synthesis, structural characterization and catalytic activity of chlororuthenium(II) complexes with substituted Schiff base/phosphine ancillary ligands
Author:
Chen Chong1, Wu Fule1, Ji Jiao1, Jia Ai-Quan1, Zhang Qian-Feng1
Affiliation:
1. Institute of Molecular Engineering and Applied Chemistry , Anhui University of Technology , Ma’anshan , Anhui 243002 , PR China
Abstract
Abstract
Treatment of [(η
6-p-cymene)RuCl2]2 with one equivalent of chlorodiphenylphosphine in tetrahydrofuran at reflux afforded a neutral complex [(η
6-p-cymene)RuCl2(κ
1-P-PPh2OH)] (1). Similarly, the reaction of [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyridine) and chlorodiphenylphosphine in methanol gave a cationic complex [Ru(bpy)2Cl(κ
1-P-PPh2OCH3)](PF6) (2), while treatment of [RuCl2(PPh3)3] with [2-(C5H4N)CH=N(CH2)2N(CH3)2] (L1) in tetrahydrofuran at room temperature afforded a ruthenium(II) complex [Ru(PPh3)Cl2(κ
3-N,N,N-L1)] (3). Interaction of the chloro-bridged complex [Ru(CO)2Cl2]
n
with one equivalent of [Ph2P(o-C6H4)CH=N(CH2)2N(CH3)2] (L2) led to the isolation of [Ru(CO)Cl2(κ
3-P,N,N-L2)] (4). The molecular structures of the ruthenium(II) complexes 1–4 have been determined by single-crystal X-ray crystallography. The properties of the ruthenium(II) complex 4 as a hydrogenation catalyst for acetophenone were also tested.
Funder
National Natural Science Foundation of China
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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