Preparation of Wood with Thermoplastic Properties, Part 1. Classical Synthesis

Abstract

Summary Aspen wood (Populus tremula) as sawdust was chemically modified through a two-step procedure: esterification with maleic anhydride and subsequent oligoesterification with glycidyl methacrylate and maleic anhydride. Chemical analyses and infra-red spectroscopy revealed the differences in the chemical composition and structure of wood as a result of this treatment. These changes were also reflected by a hygroscopicity test and thermal analyses such as thermogravimetry and thermomechanical analysis. The esterified wood showed an increased hygroscopicity and a decreased thermal stability compared to unmodified wood. In contrast, the oligoesterified wood demonstrated a reduced hygroscopicity and a comparable thermal stability up to about 200°C. The thermomechanical analysis of oligoesterified wood clearly showed a significant softening phenomenon in the range 80–140°C, a direct evidence of the thermoplastic properties gained by this chemical modification.