Poly-L-lactide nanofibers by electrospinning – Influence of solution viscosity and electrical conductivity on fiber diameter and fiber morphology

Author:

Zeng Jun1,Haoqing Hou1,Schaper Andreas2,Wendorff Joachim H.1,Greiner Andreas1

Affiliation:

1. 1Philipps-University Marburg, Department of Geosciences and Scientific Center for Materials Science, Hans-Meerwein-Str., 35032 Marburg.

2. 2Philipps-University Marburg, Department of Chemistry, Hans-Meerwein-Str., 35032 Marburg.

Abstract

Abstract Poly-L-lactide (PLA) fibers were obtained by electrospinning of PLA / dichloromethane solutions. Formation of beaded fibers combined with decreased fiber diameters were observed for low PLA concentrations in solution. Increase of the electrical conductivity by addition of pyridinium formiate (PF) caused a significant reduction of bead formation. The electrospinning of dilute PLA / PF / dichloromethane solutions resulted in PLA nanofibers. Systematic variations clearly identified the solution viscosity and the electrical conductivity at otherwise fixed parameters (surface tension, molecular weight, electrode geometry, electrical field, etc.) as crucial parameters for the formation of beads upon electrospinning of PLA / dichloromethane solutions.

Publisher

Walter de Gruyter GmbH

Subject

Polymers and Plastics,Physical and Theoretical Chemistry,General Chemical Engineering

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