Synthesis, Crystal Structure and Electrochemical Studies of a Hydrazone Schiff Base Complex of Titanium(IV)-Reference-Cited by-同舟云学术

Synthesis, Crystal Structure and Electrochemical Studies of a Hydrazone Schiff Base Complex of Titanium(IV)

Published:2009-04-01 Issue:4 Volume:64 Page:409-414
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Monfared Hassan Hosseini¹,Nazari Majid¹,Mayer Peter²,Kamyabi Mohammad-Ali¹,Erxleben Andrea³,Asgari Zohre¹

Affiliation:

1. Department of Chemistry, Faculty of Sciences, Zanjan University 45195-313, Zanjan, I.R. Iran

2. Fakultät für Chemie und Pharmazie, Ludwig-Maximilians-Universität München, Butenandtstraße 5 – 13, Haus D, D-81377 München, Germany

3. NUI Galway, School of Chemistry, Galway, Ireland

Abstract

The in situ formed hydrazone Schiff base ligand (E)-N´-(2-hydroxy-3-methoxybenzylidene)- benzohydrazide (L2−) reacts with bis(acetylacetonato)titanium(IV) oxide in methanol to a mononuclear [Ti(L)(OCH3)(acac)] complex which crystallizes in the monoclinic space group P21/c, a = 18.2786(13), b = 8.2609(5), c = 13.9008(10) Å , β = 96.809(3)° with Z = 4. Cyclic voltammetric experiments of the species in acetonitrile solution reveals a reversible peak at Eo´ = −0.768 V (vs. Ag/AgCl) relating to the TiIV/TiIII redox process.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2009-0409/pdf

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