The effect of MgTiO 3 Adding on Inclusion Characteristics

Author:

Chen Xu12,Mingya Zhang12,Jianli Li32,Songlin Ran123,Mengwei Shan12,Qiang Yue1,Hui Kong12

Affiliation:

1. School of Metallurgical Engineering, Anhui University of Technology , Maanshan, Anhui , 243002, P R China

2. Key Laboratory of Metallurgical Emission Reduction & Resources Recycling (Anhui University of Technology), Ministry of Education , Maanshan, Anhui , 243002 , P R China )

3. The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology , Wuhan, Hubei , 430081 , P R China

Abstract

Abstract MgTiO3 powder was directly added into molten steel at 1873K, and its effect on inclusion characteristics was studied by a scanning electron microscope and an energy dispersive spectrometer. Thermodynamic calculation indicates that MgTiO3 is unstable in molten steel and may decompose into [Ti], [O] and MgO. However, only Ti-bearing inclusions were observed in the treated sample, and Mg-bearing inclusions were absent. This can be explained by the features of wettability and stability for MgO. Compared with a Non-treated sample, both oxide and coarse MnS in treated sample were refined. For the oxide, this originates from the formation of Ti-bearing inclusion. For coarse MnS, this may be due to the fact that Ti can aggravate S segregation. Besides, this aggravation makes coarse MnS less globular. After etching, it was found that in the treated sample, Ti-bearing inclusion can induce the nucleation of intragranular acicular ferrites. This appearance was totally different from that of Non-treated sample, and indicates the effectiveness of external adding method in oxide metallurgy.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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