A bioinspired strategy for poly(3,4-ethylenedioxypyrrole) films with strong water adhesion

Author:

Sathanikan Ananya1,Guittard Frédéric1,Darmanin Thierry2

Affiliation:

1. Université Côte d’Azur, NICE Lab, IMREDD , 61-63 Av. Simon Veil , 06200 Nice , France

2. Université Côte d’Azur, NICE Lab, IMREDD , 61-63 Av. Simon Veil , 06200 Nice , France , Tel.: (+33)492076159, Fax: (+33)492076156

Abstract

Abstract Using a bioinspired approach, we prepare poly(3,4-ethylenedioxypyrrole) (PEDOP) films with parahydrophobic properties, characterized by high apparent water contact angle and strong water adhesion. The films are made by electropolymerization and the influence of substitution by an alkyl chain of various length (from C4H9 to C14H29) on the 3,4-ethylenedioxy-bridge is reported. More precisely, the best properties are obtained from a length of C12H25 due to the formation of spherical nanoparticles.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

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