Zippeite from Cap Garonne, France: an example of reticular twinning

Author:

Plášil Jakub1,Petříček Václav1,Mills Stuart J.2,Favreau Georges3,Galea-Clolus Valérie4

Affiliation:

1. Institute of Physics of the Czech Academy of Sciences , Na Slovance 2 , 182 21 Praha 8 , Czech Republic

2. Geosciences, Museums Victoria , GPO Box 666 , Melbourne, Victoria 3001 , Australia

3. 421 Avenue Jean Monnet , Aix-en-Provence 13090 , France

4. 10 rue Combe Noire , Sollies-Toucas 83210 , France

Abstract

Abstract We describe here the case of twinning by reticular (pseudo)merohedry in case of natural zippeite crystal from Cap Garonne, France. The twin is by two-fold rotation in [100] and it is a first document of this type of twinning in zippeite-related minerals and compounds. Zippeite crystals from Cap Garonne mine, France, were studied by single-crystal X-ray diffraction [a=8.7243(4), b=13.9337(7), c=8.8741(4) Å, β=104.243(5) and V=1045.59(9) Å3, Z=2, in C2/m]; refinement taking into account of the twinning resulted in R=2.81% for 1596 reflections with [I>3σ(I)] and refined twin fraction 0.7773(9):0.2227(9).

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Reference18 articles.

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2. S. V. Krivovichev, J. Plášil, Mineralogy and crystallography of uranium. In Uranium, from Cradle to Grave, (Eds. P. C. Burns, G. E. Sigmon) Mineralogical Association of Canada Short Course, Vol. 43, Mineralogical Society of Canada, Winnipeg, MB, p. 15, 2013.

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