Magnetic studies of 0.7(Fe2O3)/0.3(ZnO) nanocomposites in nanopowder form and dispersed in polymer matrix

Author:

Typek Janusz1,Wardal Kamil1,Zolnierkiewicz Grzegorz1,Szymczyk Anna1,Guskos Nikos,Narkiewicz Urszula2,Piesowicz Elzbieta3

Affiliation:

1. Institute of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

2. Institute of Chemical and Environment Engineering, West Pomeranian University of Technology, K. Pulaskiego10, 70-322 Szczecin, Poland

3. Institute of Material Engineering, West Pomeranian University of Technology, al. Piastów 19, 70-310 Szczecin, Poland

Abstract

Abstract Magnetic properties of 0.7(Fe2O3)/0.3(ZnO) nanocomposite synthesized by traditional wet chemistry method and containing only two phases: ZnO (nonmagnetic) and ZnFe2O4 (magnetic, with nanocrystallites of average size 12 nm, but forming large agglomerates, up to 100 nm in size) were studied by DC magnetization and ferromagnetic resonance (FMR). The investigated nanocomposite was either in a form of nanopowder or dispersed at concentration of 0.1 wt.% in poly(ethylene naphthalate-block-tetramethylene oxide) PTMO-b-PEN polymer matrix. Similarities and differences in magnetic behavior of these two samples revealed by the study of static magnetization and FMR spectra have been discussed relative to different morphologies and the associated variation of interparticle interactions. Moreover, thermal and thermo-oxidative stability of the nanocomposite and the neat polymer have been studied by thermogravimetric method.

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference25 articles.

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2. Guskos N., Zolnierkiewicz G., Typek J., Sibera D., Narkiewicz U., Rev. Adv. Mater. Sci., 23(2010), 224.

3. Guskos N., Typek J., Zolnierkiewicz G., Wardal K., Sibera D., Narkiewicz U., Rev. Adv. Mater. Sci., 29(2011), 142.

4. Kurylisz-Kudelska I., Hadzic B., Sibera D., Romcevic M., Romcevic N., Narkiewicz U., Dobrowolski W., J. Alloy. Compd., 509(2011), 3756.

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