Affiliation:
1. Institut für Anorganische Chemie der Technischen Hochschule Aachen, Templergraben 55, D-5100 Aachen
2. Institut für Anorganische Chemie der Universität Essen – Gesamthochschule, Universitätsstraße 5–7, D-4300 Essen
Abstract
From a solution of a lithium-2-boratanaphthaline Li(XBC9H7), 2a (X = Ph) and 2b (X = iPr2N), the crystalline metal derivatives Fe(XBC9H7)2 (4a, b), (tmeda)Li(XBC9H7) (5 b), and D2Rh(XBC9H7) (7b: D = C2H4; 8b: 2 D = cod) can be prepared. The metal atoms Fe and Rh are hexahapto-bonded to the boron-containing moiety of the naphthaline-type skeleton. By a crystal structure determination, the Li-atom in 5b is found to be bonded in the same way.
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23 articles.
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