A Comparative Sorption Study of Ni (II) form Aqueous Solution Using Silica Gel, Amberlite IR-120 and Sawdust

Author:

ul Haq Atta1,Jan Muhammad Rasul2,Shah Jasmin2,Sadia Maria3,Saeed Muhammad4

Affiliation:

1. Department of Chemistry , Government College University Faisalabad , Faisalabad , Pakistan , Phone: +923009302365, Email:

2. Institute of Chemical Sciences, University of Peshawar , KPK , Pakistan

3. University of Malakand, Chakdara, Dir , KPK , Pakistan

4. Department of Chemistry , Government College University Faisalabad , Faisalabad , Pakistan

Abstract

Abstract The presence of heavy metals in water causes serious problems and their treatment before incorporating into the water body is a challenge for researchers. The present study was conducted to compare the sorption study of Ni (II) using silica gel, amberlite IR-120 and sawdust of mulberry wood in batch system under the influence of pH, initial Ni (II) concentration and contact time. It was observed that sorption process was depending upon pH and maximum sorption was achieved at pH 7.0. Kinetic data were well fitted into pseudo-second order kinetic model due to high R2 values and closeness of experimental sorption capacity and calculated sorption capacity of pseudo-second order. Isotherms study showed that Langmuir is one of the most suitable choices to explain sorption data due to high R2 values. The monolayer sorption capacities of silica gel, amberlite IR-120 and sawdust were found to be 33.33, 25.19, and 33.67 mg g−1, respectively. Desorption study revealed that NaCl is one of the most appropriate desorbent. It may be concluded from this study that sawdust is a suitable sorbent due to low cost, abundant availability and recycling of the materials for further study.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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