Pd/ZrO2: An Efficient Catalyst for Liquid Phase Oxidation of Toluene in Solvent Free Conditions-Reference-Cited by-同舟云学术

Pd/ZrO2: An Efficient Catalyst for Liquid Phase Oxidation of Toluene in Solvent Free Conditions

Published:2016-11-16 Issue:2 Volume:15 Page:
ISSN:1542-6580
Container-title:International Journal of Chemical Reactor Engineering
language:en
Short-container-title:

Author:

Siddique Mohsin¹,Saeed Muhammad²,Ilyas Mohammad³⁴,Gulab Hussain¹

Affiliation:

1. Department of Chemistry, Bacha Khan University, Charsadda 24461, Pakistan

2. Department of Chemistry, Government College University Faisalabad, Faisalabad 38000, Pakistan

3. National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25000, Pakistan

4. Department of Chemistry, Qurtuba University of Science and Information Technology Peshawar, Peshawar 25120, Pakistan

Abstract

Abstract 0.1 % Pd/ZrO2 was synthesized and characterized by various physicochemical techniques and was successfully used as catalyst for solvent free oxidation of toluene in the presence of molecular oxygen using batch reactor. The catalytic performance of Pd/ZrO2 was explored in terms of effect of catalyst loading, reaction time, temperature and partial pressure of oxygen on oxidation of toluene in solvent free conditions. Pd/ZrO2 was found as a stable catalyst under the reaction conditions. Used catalyst exhibited the same catalytic efficiency as fresh catalyst under similar reaction conditions. Reaction was taking place according to Langmuir-Hinshelwood type of mechanism.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering

Link

https://www.degruyter.com/document/doi/10.1515/ijcre-2016-0093/pdf

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