Abstract
AbstractIn this review, 260 monomeric Pt(II) complexes are summarized and analyzed in which the inner coordination sphere is built up by a pair of organomonophosphines and two chlorine atoms (PtP2Cl2). These complexes are crystallized in four crystal systems: tetragonal (x17)<orthorhombic (x31)<triclinic (x90)<monoclinic (x122). The square-planar environments have cis- and trans-configurations. The former by far prevails. The mean Pt-L bond distances (cis- vs. trans-configurations) are 2.347 Å (Cl, trans to P) and 2.230 Å (P, trans to Cl) vs. 2.307 Å (Cl, trans to Cl) and 2.320 Å (P, trans to P). There are two types of isomerisms: cis-, trans- and distortion. In general, the derivatives with a cis-configuration are somewhat more distorted than that with a trans-configuration.
Reference346 articles.
1. Darstellung und Kristallstrukturen einiger Übergangsmetall - Komplexverbindungen mit Liganden mit dem Benzo methyl oxazaphosphorinan on Gerüst Synthesis Ray crystal structures of some transition - metal complexes involving ligands with the Benzo methyl;Fischer;Naturforsch b,1994
2. ray crystal structures of novel platinum II and palladium II complexes of dialkyl phosphonated phosphines;Guerrero;Organomet Chem,2002
3. Inclusion properties of palladium II and platinum II hydroquinonylphosphine complexes : the molecular and crystal structures of trans pphgH acetone pphgH dimethylformamide pphgMe;Sembiring;trans trans Chim Acta,1995
4. Preparation ofortho - substituted aryldifluorophosphines MeO or Me and some of their derivatives ray crystal structure determination of of the platinum complex;Heuer;Polyhedron,1987
5. Organodiphosphines in II coordination compounds Silicon;Melník;Phosphorus Sulfur,2014
Cited by
15 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Organodiphosphines in cis-Pt(η2-PX
n
P)(Cl)2 (n = 1,2,3) derivatives: Structural aspects;Main Group Metal Chemistry;2024-01-01
2. Organodiphosphines in Pt{η2-P(X)
n
P}(Cl)2 (n = 4, 5, 6, 7, 8, 10, 11, 15, 18) derivates: Structural aspects;Main Group Metal Chemistry;2024-01-01
3. Structural Aspects of Pt(η3–P1C2X1C2P2)(Y) Derivative Types;Crystals;2023-09-01
4. Organomonophosphines in Pt(η3-X1X2X3)(PR3), (X = N1, N2, N3; S1, S2, S3; or Te1, Te2, Te3) Derivatives: Structural Aspects;Inorganics;2023-06-03
5. Heterotridentate organodiphosphines in Pt(η3–P1X1P2)(Y) derivatives-structural aspects;Reviews in Inorganic Chemistry;2021-07-22