New Calix[4]arene-Based Amides - Their Synthesis, Conformation, Complexation

Author:

Stibor Ivan,Růžičková Martina,Krátký Rostislav,Vindyš Michal,Havlíček Jaroslav,Pinkhassik Evguenni,Lhoták Pavel,Mustafina Asiya R.,Morozova Yuliya E.,Kazakova Ella Kh.,Gubskaya Valentina P.

Abstract

New chiral calix[4]arene-based diol-diamides 1a, 1b, tetraamides 2a, 2b and 7 as well as achiral diamide 3 and tetraamides 4-6 were prepared. The conformation of 1 has been studied in solution by NMR and in solid state by X-ray crystallography. The pinched-cone conformation of the calix[4]arene skeleton in 1 was found to be stabilized by a circular array of hydrogen bonds formed by two phenolic O-H and two amidic N-H bonds at lower rim. Whereas no significant complexation of Na+ was observed in solution for diamides 1 and 3, tetraamides 2, 4, 5, and 6 give strong complexes with Na+ as confirmed by NMR titrations of 2 and 4. The influence of anions and the solvents used on complexation ability of 2 towards Na+ is negligible.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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