Extraction and complexation of alkali and alkaline earth metal cations by lower-rim calix[4]arene diethylene glycol amide derivatives

Author:

Sviben Igor12345,Galić Nives12345,Tomišić Vladislav12345,Frkanec Leo67845

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. University of Zagreb

4. 10000 Zagreb

5. Croatia

6. Laboratory of Supramolecular and Nucleoside Chemistry

7. Department of Organic Chemistry and Biochemistry

8. Ruđer Bošković Institute

Abstract

The metal-ion extraction abilities of calix[4]arene derivatives1and2are largely dependent on the type of the amide group forming the cation-binding site. Tertiary-amide derivative2was shown to be an excellent extractant for most alkali and alkaline earth cations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference58 articles.

1. C. D. Gutsche , Calixarenes: An Introduction, The Royal Society of Chemistry, Cambridge, 2nd edn, 2008

2. Calixarenes 2001, ed. Z. Asfari, V. Böhmer, J. Harrowfield and J. Vicens, Kluwer Academic Publishers, Dordrecht, 2001

3. Calixarenes, Macrocycles with(Almost) Unlimited Possibilities

4. Analytical applications of calixarenes from 2005 up-to-date

5. Coordination chemistry of calix[4]arene derivatives with lower rim functionalisation and their applications

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