Solvolysis of diphenyl amidophosphates in aqueous alcoholic media-Reference-Cited by-同舟云学术

Solvolysis of diphenyl amidophosphates in aqueous alcoholic media

Published:1980 Issue:2 Volume:45 Page:386-396
ISSN:0010-0765
Container-title:Collection of Czechoslovak Chemical Communications
language:en
Short-container-title:Collect. Czech. Chem. Commun.

Author:

Kašpárek František,Mollin Jiří

Abstract

Influence of substituent on the reaction rate of the alkali-catalyzed solvolysis of the studied compound set has been followed. The activation entropy has also been determined. The reaction products have been identified, and their concentration ratio has been determined. The reaction selectivity is mostly influenced by sterical effects in the substrate molecule. The results obtained agree with the SN2 mechanism.

Publisher

Institute of Organic Chemistry & Biochemistry

Subject

General Chemistry

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