Alkaline solvolysis of diaminophosphates
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Published:1983
Issue:1
Volume:48
Page:232-242
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ISSN:0010-0765
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Container-title:Collection of Czechoslovak Chemical Communications
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language:en
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Short-container-title:Collect. Czech. Chem. Commun.
Author:
Mollin Jiří,Láznička Jiří,Kašpárek František
Abstract
Mechanism of alkaline solvolysis of phenyl diaminophosphates is discussed on the basis of its selectivity, activation entropy and steric effects. All methods used show that the reaction proceeds by SN2 mechanism via an intermediate, containing a pentavalent phosphorus.
Publisher
Institute of Organic Chemistry & Biochemistry
Subject
General Chemistry
Cited by
1 articles.
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1. Reactions of Compounds of the Nonmetallic Elements;Mechanisms of Inorganic and Organometallic Reactions;1985