Abstract
5-Bromo-6β-chloro-5α-cholestan-3β-ol (I) undergoes solvolysis to yield products of Westphalen rearrangement one of them (XXIX) undergoing further rearrangement to the A-homo-B-nor-system V. The reaction course was established by the use of suitably labeled substrates. The structures of the products and positions of the labels were determined by chemical transformations and physicochemical methods (1H, 13C NMR spectra).
Publisher
Institute of Organic Chemistry & Biochemistry
Cited by
5 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献