The influence of fucoidan on stability, adsorption and electrokinetic properties of ZnO and TiO2 suspensions

Abstract

AbstractStabilization of nano-oxide suspensions is a very important process. Nowadays, synthetic polymers are used to increase stability of the colloidal systems. However, this solution is not ecological and incompatible with the principles of green chemistry. Instead of synthetic polymers, their natural counterparts can be used. Herein, we present the use of natural bioactive polysaccharide—fucoidan as a stabilizer of nano-zinc(II) and nano-titanium(IV) oxide suspensions. These two oxides are commercially available and are widely used in the cosmetic and pharmaceutical industries. The turbidimetric studies (Turbiscan Lab) showed that the addition of fucoidan leads to the increase of stability and that the effect depends on the polymer concentration. To fully describe the systems’ stability, the adsorption (UV–Vis and FT-IR/PAS) and the electrokinetic properties (zeta potential and surface charge density) were studied. The obtained results indicate that fucoidan adsorbs by the electrostatic and non-electrostatic interactions on the used oxides forming the tight adsorption layer. The following paper thoroughly explains the stabilization mechanism of fucoidan toward the nano-oxide suspensions. Moreover, the presented results could be useful in the preparation of new cosmetic and pharmaceutical products containing nano-oxides.