Hydrolysis and condensation behavior of tetraethoxysilane, hexaethoxydisiloxane, and octaethoxytrisiloxane-Reference-Cited by-同舟云学术

Hydrolysis and condensation behavior of tetraethoxysilane, hexaethoxydisiloxane, and octaethoxytrisiloxane

Published:2023-07-27 Issue:2 Volume:108 Page:377-391
ISSN:0928-0707
Container-title:Journal of Sol-Gel Science and Technology
language:en
Short-container-title:J Sol-Gel Sci Technol

Author:

Sato Yohei^ORCID,Sugimoto Asahi,Iwashina Tatsuya^ORCID,Hayami Ryohei^ORCID,Yamamoto Kazuki^ORCID,Gunji Takahiro^ORCID

Abstract

AbstractIn the initial stage of the hydrolysis–condensation of tetraethoxysilane (TEOS), hexaethoxydisiloxane (HEDS) and octaethoxytrisiloxane (OETS) are formed. However, little is known about the hydrolysis–condensation of HEDS and OETS. In this study, the hydrolysis–condensation of TEOS, HEDS, and OETS was investigated. HEDS and OETS were synthesized from diethoxy(diisocyanato)silane, a raw material with controllable functionality. The hydrolysis of TEOS, HEDS, and OETS was analyzed by mass spectroscopy, gel permeation chromatography, and nuclear magnetic resonance. The hydrolysis–condensation product of TEOS was a three-dimensional network-type polysiloxane. The hydrolysis–condensation product of HEDS consisted mainly of four-membered cyclic siloxane. The hydrolysis–condensation product of OETS consisted mainly of various membered cyclic siloxanes. Graphical Abstract

Publisher

Springer Science and Business Media LLC

Subject

Materials Chemistry,Condensed Matter Physics,Biomaterials,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials

Link

https://link.springer.com/content/pdf/10.1007/s10971-023-06159-x.pdf

Reference53 articles.

1. Dislich H (1971) New routes to multicomponent oxide glasses. Angew Chem Int Ed Engl 10:363–370. https://doi.org/10.1002/anie.197103631

2. Abe Y, Gunji T (2004) Oligo‐ and polysiloxanes. Prog Polym Sci 29:149–182. https://doi.org/10.1016/j.progpolymsci.2003.08.003

3. Cihlář J (1993) Hydrolysis and polycondensation of ethyl silicates. 1. Effect of pH and catalyst on the hydrolysis and polycondensation of tetraethoxysilane (TEOS). Colloids Surf A 70:239–251. https://doi.org/10.1016/0927-7757(93)80298-S

4. Harris MT, Brunson RR, Byers CH (1990) The base-catalyzed hydrolysis and condensation reactions of dilute and concentrated TEOS solutions. J Non Cryst Solids 121:397–403. https://doi.org/10.1016/0022-3093(90)90165-I

5. Tejedor-Tejedor MI, Paredes L, Anderson MA (1998) Evaluation of ATR−FTIR spectroscopy as an “in situ” tool for following the hydrolysis and condensation of alkoxysilanes under rich H2O conditions. Chem Mater 10:3410–3421. https://doi.org/10.1021/cm980146l

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