Influence of Epoxidized Natural Rubber of the thermoformability of Poly(Lactic Acid) biopolymer films using elevated temperature ball burst tests

Author:

Tábi T.ORCID,Gere D.,Csézi G.,Pölöskei K.

Abstract

AbstractIn this paper, we investigated the thermoformability of Epoxidized Natural Rubber (ENR)-filled Poly(Lactic Acid) (PLA) films using elevated temperature tensile and ball burst tests. Three different d-Lactide contents of PLA were used to be able to analyze the effect of crystallization and crystallinity. We observed that the ENR acted as a nucleating agent in PLA when the blend was cooled from melt or cold crystallized, but it retarded the drawing-induced crystallization of PLA at elevated temperature tensile testing since ENR droplets acted as obstacles. The effect of NR on PLA crystallization was also found to be dependent on d-Lactide content. In the ball burst test, different behaviors were observed for PLA with the lowest d-Lactide content, which was caused by the complex stress state that even more induced crystallization of PLA and then a single-axis tensile test.

Funder

National Research, Development and Innovation Office

Magyar Tudományos Akadémia

Nemzeti Kutatási, Fejlesztési és Innovaciós Alap

Budapest University of Technology and Economics

Publisher

Springer Science and Business Media LLC

Subject

Physical and Theoretical Chemistry,Condensed Matter Physics,Polymers and Plastics,Materials Chemistry

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