Determination of sediment sources following a major wildfire and evaluation of the use of color properties and polycyclic aromatic hydrocarbons (PAHs) as tracers

Abstract

Abstract Purpose This research aimed to determine if a severe wildfire caused changes in the source of sediment being delivered to downstream aquatic systems and evaluate the use of polycyclic aromatic hydrocarbons (PAHs) and color properties as tracers. Methods Sediment samples were collected from 2018 to 2021 in three tributaries impacted by the 2018 Shovel Lake wildfire and from two sites on the mainstem of the Nechako River, British Columbia. Source samples were collected from burned and unburned soils as well as from channel banks and road-deposited sediment. Samples were analyzed for color properties and for the 16 US Environmental Protection Agency priority PAHs. After statistical tests to determine the conservatism and ability to discriminate between sources by the tracers, the MixSIAR unmixing model was used, and its outputs were tested using virtual mixtures. Result In the tributaries, burned topsoil was an important contributor to sediment (up to 50%). The mainstem Nechako River was not influenced as significantly by the fires as the greatest contributor was banks (up to 89%). The color properties provided more realistic results than those based on PAHs. Conclusion In smaller watersheds, the wildfire had a noticeable impact on sediment sources, though the impacts of the fire seemed to be diluted in the distal mainstem Nechako River. Color tracers behaved conservatively and discriminated between contrasting sources. Due to their low cost and reliability, they should be considered more widely. While PAHs did not work in this study, there are reasons to believe they could be a useful tracer, but more needs to be understood about their behavior and degradation over time.