Numerical simulations and experiments on droplet coalescence dynamics over a liquid–air interface: mechanism and effect of droplet-size/surface-tension

Abstract

AbstractPresent study is on partial/complete coalescence dynamics of a droplet (surrounded by air) over a horizontal pool of the same liquid. Experimental and numerical studies are presented for both isopropanol and glycerol droplet of a constant diameter. Numerical study is presented in more detail for the isopropanol droplet to study the effect of diameter ($$D=0.035-6.7 mm$$ D = 0.035 - 6.7 m m ) and surface tension coefficient ($$\gamma =2-200 mN/m$$ γ = 2 - 200 m N / m ) on the coalescence dynamics. For partial coalescence of an isopropanol droplet and complete coalescence of a glycerol droplet, excellent agreement is demonstrated between our numerically and experimentally obtained interface dynamics; and a qualitative discussion on the mechanism of the partial and complete coalescence is presented. Three regimes of partial coalescence − viscous, inertio-capillary and gravity − proposed in the literature for a liquid-liquid system are presented here for the present liquid-air system while studying the effect of diameter of the isopropanol droplet. Probably for the first time in the literature, our numerical study presents a flow and vorticity dynamics based quantitativeevidence of the coalescence-mechanism, analogy with a freely vibrating Spring-Mass-Damper System, the gravity regime for a liquid-gas system, and the effect of surface tension coefficient $$\gamma$$ γ based coalescence dynamics study. The associated novel $$\gamma$$ γ based droplet coalescence regime map presents a critical Ohnesorge number $$Oh_{c}$$ O h c and critical Bond number $$Bo_{c}$$ B o c for a transition from partial to full coalescence; and such critical values are also presented for the transition under effect of the droplet diameter. The critical values based transition boundaries, obtained separately for the varying D and varying $$\gamma$$ γ , are demonstrated to be in excellent agreement with a correlation reported in the literature.