Effective removal of hexavalent chromium from water by sustainable nano-scaled waste avocado seeds: adsorption isotherm, thermodynamics, kinetics, and error function

Abstract

Abstract In the current investigation, an efficient low-cost nano-scaled material was prepared from waste avocado seeds (NASs) and employed as a sustainable nanosorbent for removal of hexavalent chromium ions. The adsorption and surface characteristics with respect to the availability of functional groups, basic component elements, and structural properties of NASs were achieved by different techniques. Analysis of NASs referred to the presence of carbon and oxygen contents providing 97.21%. The NASs particles were homogenously identified and ranged between 18.68 and 19.05 nm. The impact of various affecting adsorption parameters on hexavalent chromium ions removal was elaborated and optimized at pH 2.0, NASs dose 10 mg, contact time 30 min, and temperature 25 °C by the batch adsorption assay. Fifteen linear and nonlinear modeling tests were applied to evaluate the adsorption isotherms and arranged in the following fitting order: Tempkin < BET < Dubinin-Radushkevich < Generalized < Halsey ˂ Flory–Huggins < Freundlich < Harkins–Jura ˂ Langmuir for linear formulas and Weber-van Vliet < Langmuir < Generalized < Radke–Prausnitz (II) < Radke–Prausnitz (III) < Fritz-Schlunder IV < Baudu < Multilayer < Fritz-Schlunder V < Toth for nonlinear formulas with 2 to 5 parameters. Linear and nonlinear pseudo-second-order models, intraparticle diffusion, and Elovich models were also scrutinized, and both pore diffusion and film were similarly involved in the rate-limiting step. The values of ΔS° (0.21 kJ/mol), ΔH° (− 41.02 kJ/mol) and ΔG° (− 28.30 to − 19.97 kJ/mol) at high concentration of hexavalent chromium (50 mg L−1) and a temperature range of 20–60 °C reflected the disordering, spontaneously exothermic adsorption process. The activation energy (Ea) was also confirmed to include the diffusion process at the activation energy in the rate-limiting step. The potential application of NASs in hexavalent chromium removal from wastewater, seawater, and tap water as real aqueous matrices referred to excellent percentage removal values in the range from 98.44 to 98.86%. Based on the outlined results, one can deduce that excellent performance and efficiency for removal of high hexavalent chromium concentration at high temperature, low nanosorbent mass, and low pH from different aqueous matrices were accomplished by the evaluated NAS nanosorbent. Accordingly, the investigated NAS nanosorbent is recommended to apply in high stress industrial and wastewater treatment plants.