Flexible Molybdenum Disulfide/Carbon Nanotube Composite Films for Thermoelectric Applications

Author:

Li Qinglin1,Li Ping1,Li Yanke1,Sidike Saiyaer1,Xu Yueling1,Wang Yuchen2,Hu Zhi2,Guo Mingming1,Zhang Hanqi3,Zhang Yichuan2ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Soft-Matter Material Chemistry and Function Manufacturing, Southwest University, Chongqing 400715, China.

2. Chongqing Copolyforce New Materials Co, Ltd, Chongqing 401332, China.

3. National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150001, China.

Abstract

Earth-abundant molybdenum disulfide (MoS 2 ) shows a high application potential in thermoelectric (TE) field owing to its high Seebeck coefficient. However, the main obstacle to achieve high TE performance for the MoS 2 material is its poor electrical conductivity. In this work, the flexible MoS 2 /single-walled carbon nanotube (SWCNT) films with enhanced TE performance were fabricated via hydrothermal reaction, solution mixing, and subsequent vacuum filtration. The strong S–π interaction and the energy filtering effect at the MoS 2 /SWCNT interface produced an impressive power factor value of 107.99 ± 4.98 μW·m −1 ·K −2 for the MoS 2 /SWCNT composite films. In addition, the TE performance had high stability on bending deformation. Finally, at a temperature difference of 50 K, the assembled TE device of MoS 2 /SWCNT films exhibited good output performance. This work provides a feasible reference to optimize the TE performance of MoS 2 materials and demonstrates a high potential of flexible MoS 2 -based composites in TE applications.

Funder

Natural Science Foundation of Chongqing, China

Fundamental Research Funds for the Central Universities

the Science and Technology Innovation, Venture Capital Special Projects of TIANDI Science Technology Co. Ltd

CCTEG Chongqing Research Institute

Xinjiang Uygur Autonomous Region Colleges and Universities Basic Scientific Research Operating Expenses Scientific Research Projects

Publisher

American Association for the Advancement of Science (AAAS)

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