Sensitivity Analysis of Absorption Cycle Fluid Thermodynamic Properties

Author:

Palmer S. C.1,Shelton S. V.2

Affiliation:

1. Mechanical Engineering Department, United States Naval Academy, Annapolis, MD 21402-5042

2. G. W. W. School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0405

Abstract

Absorption heat pump technology may be improved by new cycle configurations by new working fluids. In this study, the effect of hypothetical working fluids on performance improvement is explored. The performance of two cycles is studied using three fluid property sources for ammonia/water, i.e., curve-fit experimental data, an ideal solution model, and the Peng-Robinson equation of state model. The models require only minimal fundamental thermodynamic property data for the two pure components. This allows investigation into the influence of each fundamental property on cycle performance, providing insight into desirable properties for new absorption fluid pairs. Variations of fundamental fluid properties are used as input to the models, showing that the volatilities of the refrigerant and absorbent have the greatest effect on cycle performance.

Publisher

ASME International

Subject

Geochemistry and Petrology,Mechanical Engineering,Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

Reference20 articles.

1. ASHRAE, 1993, Fundamentals Handbook.

2. Connon, H. A., date unknown, “A Generalized Computer Program for Analysis of Refrigeration Cycles,” Freon Products Laboratory, E.I. du Pont de Nemours and Co., Wilmington, DE.

3. Eisa M. A. R. , and HollandF. A., 1987, “A Study of the Optimum Interaction Between the Working Fluid and the Absorbent in Absorption Heat Pump Systems,” Heat Recovery Systems, Vol. 2, pp. 107–117.

4. El-Sayed Y. M. , and TribusM., 1985, “Thermodynamic Properties of Water-Ammonia Mixtures Theoretical Implementation for Use in Power Cycles Analysis,” Analysis of Energy Systems—Design and Operation, ASME AES-Vol. 1, pp. 89–95.

5. Grover G. S. , EisaM. A. R., and HollandF. A., 1988, “Thermodynamic Design Data for Absorption Heat Pump Systems Operating on Water-Lithium Chloride—Part One: Cooling,” Heat Recovery Systems and CHP, Vol. 1, pp. 33–41.

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