Characterization of Anode-Supported Solid Oxide Fuel Cells With PSCF Cathode

Author:

Haanappel V. A. C.1,Mai A.2,Uhlenbruck S.1,Tietz F.1

Affiliation:

1. Institute for Energy, Forschungszentrum Jülich, D-52425 Jülich, Germany

2. Hexis AG, Hegifeldstrasse 30, 8404 Winterthur, Switzerland

Abstract

A systematic study was initiated of anode-supported single cells with Pr0.58Sr0.4Co0.2Fe0.8O3−δ (PSCF) cathode. These solid oxide fuel cells (SOFCs) were characterized by electrochemical and diffusion and permeation measurements. In particular, the influence of various sintering temperatures of the cathode and various types of Ce0.8Gd0.2O2−δ (CGO) interlayer was investigated in more detail. Results from electrochemical measurements performed between 650°C and 800°C showed that the performance of anode-supported SOFCs with screen-printed porous CGO interlayer and a PSCF cathode was excellent. Even at 650°C, the area-specific resistance was lower than 0.5Ωcm2. The microstructure of the cathode and the performance of this type of SOFC were not obviously affected by variations in the sintering temperature of the cathode. Higher electrochemical performance, in particular, in the temperature range 650–750°C, was achieved by applying a thin and dense CGO interlayer using reactive sputtering or electron beam physical vapor deposition.

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

Reference18 articles.

1. Mai, A. , 2004, “Katalytische und Elektrochemische Eigenschaften von Eisen- und Kobalthaltigen Perowskiten als Kathoden für die Oxidkeramische Brennstoffzelle (SOFC),” Ph.D. thesis, Ruhr-Universität Bochum, Germany.

2. Ahmad-Khanlou, A. , 2000, “Alternative Werkstoffe für Komponenten der Hochtemperatur-Brennstoffzelle (SOFC) zur Herabsetzung der Betriebstemperatur,” Ph.D. thesis, Ruhr-Universität Bochum, Germany.

3. Optimisation of Processing and Microstructural Parameters of LSM Cathodes to Improve the Electrochemical Performance of Anode-Supported SOFCs;Haanappel;J. Power Sources

4. The Electrochemical Performance of Anode-Supported SOFCs With LSM-Type Cathodes Produced by Alternative Processing Routes;Mertens;ASME J. Fuel Cell Sci. Technol.

5. Sintering Behavior of (La,Sr)MnO3 Type Cathodes for Planar Anode-Supported SOFCs;Mertens;ASME J. Fuel Cell Sci. Technol.

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