One-Pot Pyrolysis to Nitrogen-Doped Hierarchically Porous Carbon Nanosheets as Sulfur-Host in Lithium–Sulfur Batteries

Author:

Zha Cheng1,Liu Shuhe1,Zhou Liexing2,Li Kongzhai1,Zhang Tianyu1

Affiliation:

1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China

2. Research Center for Analysis and Measurement, Kunming University of Science and Technology, Kunming 650093, China

Abstract

Abstract Lithium–sulfur battery is a promising energy storage device because of its high theoretical specific energy density, low cost, and environmental friendliness. Here, we prepared nitrogen-doped hierarchically porous carbon nanosheets (N-PCNS) by NaCl salt-assisted one-pot pyrolysis strategy, using NaCl, glucose, and melamine as template, carbon and nitrogen as source. Using N-PCNS hosted sulfur composite material (N-PCNS/S) as the cathode material of the lithium–sulfur battery, the first specific discharge capacity at 0.2 C is 956.7 mA h g−1, and the reversible capacity after 100 cycles is 625.9 mA h g−1, with the capacity loss of 0.34% per cycle. At the high rate of 0.5 C, the specific capacity of the first discharge is still 717.3 mA h g−1. This study provides a simple and feasible strategy for the preparation of cathode materials for lithium–sulfur batteries.

Funder

Analysis and Testing Foundation of Kunming University of Science and Technology

National Natural Science Foundation of China

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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