Some Considerations on the Electrolysis of Water from Sodium Hydroxide Solutions-Reference-Cited by-同舟云学术

Some Considerations on the Electrolysis of Water from Sodium Hydroxide Solutions

Published:2000-12-01 Issue:2 Volume:123 Page:143-146
ISSN:0199-6231
Container-title:Journal of Solar Energy Engineering
language:en
Short-container-title:

Author:

Fletcher Edward A.¹

Affiliation:

1. Department of Mechanical Engineering, University of Minnesota, 111 Church Street S.E., Minneapolis, Minnesota 55455

Abstract

The unusually high solubilities and thermal coefficients of solubility of the alkali metal hydroxides make them attractive candidates for high-temperature electrolytic processes to produce high-pressure hydrogen. The feasibility of using strong sodium hydroxide (to keep down the saturation pressure of the condensed phase) electrolysis (to facilitate the separation of the hydrogen from oxygen over a liquid phase) at high temperatures (to increase the energy efficiency by substitution of process heat for electric power) and to increase the production rate in a given cell (by increasing the specific conductance of the working fluid) is explored and discussed. Suggestions are made for future research.

Publisher

ASME International

Subject

Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment

Link

http://asmedigitalcollection.asme.org/solarenergyengineering/article-pdf/123/2/143/5712403/143_1.pdf

Reference21 articles.

1. Fletcher, E. A. , 1999, “Solarthermal and Solar Quasi-Electrolytic Processing and Separations: Zinc from Zinc Oxide as an Example,” Ind. Eng. Chem. Res. 38, No. 6, pp. 2275–2282.

2. Fletcher, E. A., and Noring, J. E., 1983, “High Temperature Electrothermal Processing: Zinc from Zinc Oxide,” Energy (Oxford) 8, No. 4, pp. 247–254.

3. Wenthorf, R. H., and Hanneman, R. E., 1974, “Thermochemical Hydrogen Generation,” Science 185, p. 311311.

4. Chao, R. E. , 1974, “Thermochemical Water Decompression Processes,” Ind. Eng. Chem. Prod. Res. Dev. 13, No. 2, p. 9494.

5. Fletcher, E. A., and Moen, R. L., 1977, “Hydrogen and Oxygen from Water,” Science 197, pp. 1050–1056.

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