Binder-Free Thin-Film Electrode Fabricated by Spray Drying Method: A Case of LiFePO4

Author:

Guo Xiaolong1,Lan Tu1,Feng Xiang1,Li De1,Chen Yong1

Affiliation:

1. State Key Laboratory on Marine Resource Utilization in South China Sea, Hainan Provincial Key Laboratory of Research on Utilization of Si-Zr-Ti Resources, School of Materials Science and Engineering, Hainan University, Haikou 570228, China

Abstract

Abstract With the development of portable electronic devices, it is an urgent demand to miniaturize energy storage components, especially for Li-ion batteries, and the thin-film electrode is a promising miniaturization strategy. In this work, we successfully fabricated a binder-free thin-film electrode of LiFePO4/C by a spray drying method. According to the scanning electron microscopy, the Al-foil substrate was coated with a porous LiFePO4/C layer of ca. 4 µm thick, and the X-ray diffraction and the Raman spectra reveal the good crystallization of LiFePO4 and the presence of amorphous carbon. The as-prepared electrode exhibits an excellent cycle stability, which works quite good even after 2000 cycles. Thereby, we suggested that the as-prepared binder-free thin-film electrode can be potentially applied in the field of all-solid-state, flexible, and micro Li-ion batteries.

Funder

Hainan University's Scientific Research Foundation

National Natural Science Foundation of China

Natural Science Foundation of Hainan Province

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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