Theoretical Calculation of the Electrical Potential at the Electrode/Electrolyte Interfaces of Solid Oxide Fuel Cells

Author:

Celik Ismail1,Pakalapati S. Raju2,Salazar-Villalpando Maria D.2

Affiliation:

1. West Virginia University, Mechanical and Aerospace Engineering Department, PO Box 6106, Morgantown, WV 26506

2. Mechanical and Aerospace Engineering Department, West Virginia University, Morgantown, WV, USA

Abstract

A new semi-empirical model is formulated to calculate the potential differences at the cathode/electrolyte and electrolyte/anode interfaces separately for solid oxide fuel cells. The new model is based on a reduced reaction mechanism, and it accounts for the oxygen ion concentration at these interfaces. The model also considers the Gibbs free energy for the two electrode interfaces seperately. Results from case studies demonstrate the great potential of the proposed model

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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