A Fast, Accurate Real Gas Equation of State for Fluid Dynamic Analysis Applications

Author:

Aungier R. H.1

Affiliation:

1. Elliott Company, Jeannette, PA 15644-1473

Abstract

A modified form of the Redlich-Kwong two-parameter equation of state is presented. The modified equation employs the acentric factor and the critical point compressibility factor as additional parameters to improve its accuracy and to extend its application range to include the critical point. This modified equation is as simple as the original form, yet achieves substantially better prediction accuracy, including thermodynamic parameters such as enthalpy and entropy. Results from this equation, the original equation, and three other popular modified forms are compared with gas property data for several compounds to demonstrate its improved accuracy and increased application range. Practical application limits to the other modified forms are identified to guide current users of those methods.

Publisher

ASME International

Subject

Mechanical Engineering

Reference9 articles.

1. Akin, S. W., 1950, “The Thermodynamic Properties of Helium” Trans. ASME, Aug., pp. 751–757.

2. Barnes, F. J., 1973, Ph.D. thesis, Department of Chemical Engineering, University Of California, Berkeley.

3. Canjar, L. N., and Manning, F. S., 1967, Thermodynamic Properties And Reduced Correlations For Gases, Gulf Publishing, Houston.

4. NIST, 1991, “NIST Thermodynamic Properties Of Refrigerants And Refrigerant Mixtures Database,” National Institute of Standards and Technology, Gaithersburg, MD.

5. Pitzer K. S. , 1955, Journal of the American Chemical Society, Vol. 77, pp. 3427–3440.

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