Structural Evolution and Formation Mechanism of LiNiO2 During High-Temperature Solid-State Synthesis-Reference-Cited by-同舟云学术

Structural Evolution and Formation Mechanism of LiNiO2 During High-Temperature Solid-State Synthesis

Published:2019-02-19 Issue:3 Volume:16 Page:
ISSN:2381-6872
Container-title:Journal of Electrochemical Energy Conversion and Storage
language:en
Short-container-title:

Author:

Deng Shiyi¹,Xue Longlong²,Li Yunjiao³,Lin Zehua²,Li Wei⁴,Chen Yongxiang²,Lei Tongxing²,Zhu Jie²,Zhang Jinping²

Affiliation:

1. School of Metallurgy and Environment, Central South University, Changsha 410083, China; Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, ON M5S 3E5, Canada

2. School of Metallurgy and Environment, Central South University, Changsha 410083, China

3. School of Metallurgy and Environment, Central South University, Changsha 410083, China e-mail:

4. School of Metallurgy and Environment, Central South University, Changsha 410083, China; Citic Dameng Mining Industries Limited, Nanning 530028, China

Abstract

The processes and mechanisms of LiNiO2 synthesis during the high-temperature solid state method, using Ni(OH)2 precursor and different lithium salts (Li2CO3 and LiOH), were revealed by the thermal (TG–DTA) and structural (X-ray diffraction (XRD)) analyses. Morphology characterization (scanning electron microscopy (SEM)) and the soluble lithium titration are carried out to support the findings. The results show that the synthetic processes of LiNiO2 generally include raw materials' dehydration, oxidation, and combination; also, the existence of lithium salts makes the oxidation of Ni(OH)2 relatively easier. Comparing the two lithium salts involved in the reactions, LiOH will bring about a transition oxide (Ni8O10) and lower the initial reaction temperature for LiNiO2 generation. In addition, a decent temperature under 800 °C, a preheat treatment in 500–600 °C, and a properly longer heating time are suggested to be significant for obtaining the ideal LiNiO2 materials.

Funder

Science and Technology Department of Guangxi Zhuang Autonomous

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

Link

http://asmedigitalcollection.asme.org/electrochemical/article-pdf/doi/10.1115/1.4042552/6133272/jeecs_016_03_031004.pdf

Reference31 articles.

1. A Brief Review: Past, Present and Future of Lithium Ion Batteries;Russ. J. Electrochem.,2016

2. Research on Advanced Materials for Li+ Ion Batteries;Adv. Mater.,2010

3. Lithium Batteries: Status, Prospects and Future;J. Power Sources,2010

4. Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries;Angew. Chem. Int. Ed.,2015

5. Cation Ordering of Zr-Doped LiNiO2 Cathode for Lithium-Ion Batteries;Chem. Mater.,2018

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