Affiliation:
1. Department of Mechanical and Industrial Engineering, Northeastern University, Boston 02115, MA
Abstract
The rate-controlled constrained-equilibrium (RCCE) method is a reduction technique based on local maximization of entropy or minimization of a relevant free energy at any time during the nonequilibrium evolution of the system subject to a set of kinetic constraints. In this paper, RCCE has been used to predict ignition delay times of low temperatures methane/air mixtures in shock tube. A new thermodynamic model along with RCCE kinetics has been developed to model thermodynamic states of the mixture in the shock tube. Results are in excellent agreement with experimental measurements.
Subject
Geochemistry and Petrology,Mechanical Engineering,Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment
Cited by
16 articles.
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