A Fundamental Study on the Chemical Stability of La1−xSrxCo0.2Fe0.8O3−δ Cathodes for Intermediate Temperature Solid Oxide Fuel Cells

Author:

Qiu Yufeng1,Pu Jian1,Li Jian2,Liu Yihui34,Hua Bin5

Affiliation:

1. Center for Fuel Cell Innovation, School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China

2. Center for Fuel Cell Innovation, School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China e-mail:

3. Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China;

4. Hubei Collaborative Innovation Center for Automotive Components Technology, Wuhan University of Technology, Wuhan 430070, China e-mail:

5. Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 1H9, Canada

Abstract

The chemical stability of La1−xSrxCo0.2Fe0.8O3−δ (x = 0, 0.4, 0.6, and 1) oxides before and after annealing at 750 °C in air is investigated by field emission scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), and environmental transmission electron microscopy (TEM). Results indicate that Sr surface segregation has initially occurred at the sintering stage, and then, the secondary-phase particles are formed with increasing the heat-treatment time at 750 °C in air. Increasing Sr content accelerates Sr segregation on the surface, because of two driving forces including interaction forces in the crystal lattice and thermal activation. AES and XPS results reveal that Sr and Co segregations toward the surface have great contributions to the chemical instability of La1−xSrxCo1−yFeyO3−δ (LSCF) during annealing.

Funder

National Natural Science Foundation of China

Huazhong University of Science and Technology

Publisher

ASME International

Subject

Mechanical Engineering,Mechanics of Materials,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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